Simple formula for asymmetric Marcus–Hush kinetics
نویسندگان
چکیده
منابع مشابه
Simple formula for asymmetric Marcus–Hush kinetics
The Marcus–Hush theory of electron transfer has seen increasing use as a predictive alternative to the phenomenological Butler–Volmer (BV) equation for Faradaic reactions kinetics. Here, we analyze and simplify the asymmetric Marcus–Hush (AMH) model, first proposed by Marcus and recently used by Compton’s group to fit experimental data that exhibit two different reorganization energies, dependi...
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The Marcus–Hush–Chidsey (MHC) model is well known in electro-analytical chemistry as a successful microscopic theory of outer-sphere electron transfer at metal electrodes, but it is unfamiliar and rarely used in electrochemical engineering. One reason may be the difficulty of evaluating the MHC reaction rate, which is defined as an improper integral of the Marcus rate over the Fermi distributio...
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ژورنال
عنوان ژورنال: Journal of Electroanalytical Chemistry
سال: 2015
ISSN: 1572-6657
DOI: 10.1016/j.jelechem.2015.04.018